Counter-ions at charged walls: two-dimensional systems.
نویسندگان
چکیده
We study equilibrium statistical mechanics of classical point counter-ions, formulated on 2D Euclidean space with logarithmic Coulomb interactions (infinite number of particles) or on the cylinder surface (finite particle numbers), in the vicinity of a single uniformly charged line (one single double layer), or between two such lines (interacting double layers). The weak-coupling Poisson-Boltzmann theory, which applies when the coupling constant [Formula: see text] is small, is briefly recapitulated (the coupling constant is defined as [Formula: see text] [Formula: see text] [Formula: see text] e (2) , where [Formula: see text] is the inverse temperature, and e the counter-ion charge). The opposite limit ( [Formula: see text] [Formula: see text] ∞ is treated by using a recent method based on an exact expansion around the ground-state Wigner crystal of counter-ions. These two limiting results are compared at intermediary values of the coupling constant [Formula: see text] = 2[Formula: see text] ([Formula: see text] = 1, 2, 3) , to exact results derived within a 1D lattice representation of 2D Coulomb systems in terms of anti-commuting field variables. The models (density profile, pressure) are solved exactly for any particles numbers N at [Formula: see text] = 2 and up to relatively large finite N at [Formula: see text] = 4 and 6. For the one-line geometry, the decay of the density profile at asymptotic distance from the line undergoes a fundamental change with respect to the mean-field behavior at [Formula: see text] = 6 . The like-charge attraction regime, possible for large [Formula: see text] but precluded at mean-field level, survives for [Formula: see text] = 4 and 6, but disappears at [Formula: see text] = 2 .
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عنوان ژورنال:
- The European physical journal. E, Soft matter
دوره 34 2 شماره
صفحات -
تاریخ انتشار 2011